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本文合成了铜(Ⅱ)与邻菲咯啉和草酸三元配合物[Cu(phen)(ox)(H_2O)]·H_2O(phen：1，10-邻菲咯啉；ox：草酸)，得 到了它的单晶，用 X-射线法测定了配合物的晶体结构。晶体学数据：C_(14) H_(12) CuN_2O_6，Mr=367． 80，晶型 a=8． 447(4) (?)，b=9． 696 (5) (?)，c=17． 456(8) (?)；β=103． 875(10) (?)．Z=4． V=1388． 0(12) (?)~3，F(000) =748。晶体中分子配位中心 Cu(Ⅱ)离子的配位数为5，这五个配位原子形成一个畸变的四方锥结构，配合物分子因 分子间氢键作用形成一维链状结构。
In this paper, Cu (Ⅱ) complexes with phenanthroline and oxalic acid [Cu (phen) (ox) (H_2O)] · H_2O (phen: 1,10-phenanthroline and ox: Its single crystal, X-ray method was used to determine the crystal structure of the complex. Crystallographic data: C_ (14) H_ (12) CuN_2O_6, Mr = 367. 80, Form a = 8. 447 (4) (?), B = 9. 696 (5) (?), C = 17. 456 (8) (?); Β = 103. 875 (10) (?). Z = 4. V = 1388. 0 (12) (?) ~ 3, F (000) = 748. The coordinative number of Cu (Ⅱ) ions in the crystal coordination center is 5, and the five coordination atoms form a distorted tetragonal pyramidal structure. The complex molecules form a one-dimensional chain structure due to intermolecular hydrogen bonding.