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A chiral salency complex,[Mn(Salency)(H2O)2](PF6)·2H2O 1(Salency =(R,R)-N,N’-bis(salicylidene)-1,2-cyclohexanediamine),has been prepared by the reaction of Mn(CH3COO)3·2H2O with Salency and NH4PF6,and was established by X-ray diffraction techniques.The complex crystallizes in triclinic,space group P1 with a=9.299(8),b=10.012(8),c=13.461(11),α=92.037(15),β=92.974(12),γ=93.530(18)°,V=1248.3(18)3,C20H28F6MnN2O6P,Mr = 592.35,Z=2,Dc=1.038 g/cm3,F(000)=608,μ=0.676 mm-1,the final R=0.0651 and wR=0.1880 for 5260 observed reflections with I > 2σ(I).
A chiral salency complex, [Mn (Salency) (H2O) 2] (PF6) · 2H2O 1 (Salenix = (R, R) -N, N’-bis (salicylidene) -1,2-cyclohexanediamine), has been prepared by the reaction of Mn (CH3COO) 3.2H2O with Salency and NH4PF6, and was established by X-ray diffraction techniques. The complex crystallizes in triclinic space group P1 with a = 9.299 (8), b = 10.012 (8), C = 13.461 (11) , α = 92.037 (15), β = 92.974 (12), γ = 93.530 (18) °, V = 1248.3 (18) 3, C20H28F6MnN2O6P, Mr = 592.35, Z = 2, Dc = 1.038 g / cm3, F (000) = 608, μ = 0.676 mm-1, the final R = 0.0651 and wR = 0.1880 for 5260 observed reflections with I> 2σ (I).