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： The homobinuclear complexes of Cu(II) and Ni(II) with N,N′-bis(3-Carboxyl salicyl aminal ethylene) oxalamide were synthesized, and characterized by elemental analysis, IR spectra, Uv-visible spectra, conductometry, thermogravimetry, and magnetic susceptibility measurement, which indicated the complexes own an oxalic amide bridge-linking structure. Room temperature magnetic moment data show that there are antiferromagnetic spin coupling through oxalic amide conjugated double bond, In DMF, the redox half wave potential of Cu(II) binuclear complexes have been measured by cyclic voltammetry, which proves that the Cu(II) complex has two redox waves.
: The homobinuclear complexes of Cu (II) and Ni (II) with N, N’-bis (3-Carboxyl salicyl aminal ethylene) oxalamide were synthesized, and characterized by elemental analysis, IR spectra, Uv-visible spectra, conductometry, thermogravimetry , and magnetic susceptibility measurement, which indicates the complexes own an oxalic amide bridge-linking structure. Room temperature magnetic moment data show that there are antiferromagnetic spin coupling through oxalic amide conjugated double bonds, In DMF, the redox half wave potential of Cu (II ) binuclear complexes have been measured by cyclic voltammetry, which proves that the Cu (II) complex has two redox waves.