一、引言众所周知,利用空气氧化天然气,工业气体烃,固体和液体石油产物等以制取各种有机含氧化合物——醇、醛、酸、过氧化物等——是天然资源化学加工最有前途的方法之一。这些含氧化合物作为重有机合成的原料或半成品,乃是合成对国民经济具有重大意义的高分子化合物和其它贵重有机产品的主要原料。因此烃类的氧化加工作为一个有机合成的重要方向。很久以来便引起了化学家的注意。为寻找实现烃氧化过程之最宜条件,以确定合理的工艺过程,就必须揭示氧化转化的机理。远在1892年英国化学家W.A.Bene[1]就已开始了烃氧化的实验究。一百多年来已累积了有关烃类氧化过程的一般动力学和化学机理的丰富实验材料,确定了氧 I. Introduction As we all know, the use of air oxidation of natural gas, industrial gas hydrocarbons, solid and liquid petroleum products to produce a variety of organic oxygenates - alcohols, aldehydes, acids, peroxides, etc. - is the natural resources of the most chemical processing One of the ways forward. These oxygenates, as raw materials or semi-finished products for heavy organic synthesis, are the main raw materials for the synthesis of macromolecular compounds and other valuable organic products of great significance to the national economy. Therefore, the oxidation of hydrocarbons processing as an important direction of organic synthesis. It has long been the chemist’s attention. In order to find the optimum conditions for the hydrocarbon oxidation process, in order to determine a reasonable process, we must disclose the mechanism of oxidative conversion. As far back as 1892 British chemist W.A. Boene [1] has begun the experimental study of hydrocarbon oxidation. Over a hundred years have accumulated a wealth of experimental data on the general kinetics and chemical mechanisms of hydrocarbon oxidation processes, confirming that oxygen