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本文根据实验事实和Jellinek假定,提出了合理的CSVPC和CSVPC的2价第一过渡金属配合物的热分解机理。此机理不仅较好地解释了CSVPC的TG实验现象,也比较满意地解释了CSVPC的2价第一过渡金属配合物的TG实验数据及其一些规律。CSVPC的2价第一过渡金属配合物的红外光谱,原子吸收实验值和2价第一过渡金属配合物的水合能计算值也能说明此机理的合理性。
Based on the experimental facts and the Jellinek assumption, this paper presents a reasonable thermal decomposition mechanism of the bivalent first transition metal complex of CSVPC and CSVPC. This mechanism not only explained the TG experiment of CSVPC well, but also explained the TG experimental data and some rules of the binary transition metal complex of CSVPC more satisfactorily. The results also show the rationality of this mechanism by the infrared spectrum, the atomic absorption experimental data and the calculation of the hydration energy of the bivalent first transition metal complex.