【摘 要】
：
A new inorganic-organic hybrid constructed from a-octamolybdate polyoxometalates modified by hexadtrack Cu-bpe chains, 2{[Cu(bpe)]6[α-Mo8O26]3/2}·[Cu(bpe)]3-3
【机 构】
：
Heilongjiang Provincial Key Laboratory of Biomaterials and Biological Medicine Formulation,Key Labor
论文部分内容阅读
A new inorganic-organic hybrid constructed from a-octamolybdate polyoxometalates modified by hexadtrack Cu-bpe chains, 2{[Cu(bpe)]6[α-Mo8O26]3/2}·[Cu(bpe)]3-3H2O[l, bpe=bis(4-pyridyl)ethylene], has been synthesized and structurally characterized. X-Ray diffraction analysis reveals that each a-octamolybdate cluster links six transition metal complex chains and the title compound has represented the highest connective number of M-N chains modified octamolybdate POMs to date. Note that there are two crystallographically unique [α-Mo8O26]n- clusters and eight unique copper sites, which play an important role in the overall architecture of hybrid compounds. Additionally, the electrochemical properties of the title compound were studied.
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