某些人工合成的金属卟啉,由于其活化分子氧的功能,被广泛用作生物模拟氧化反应中的催化剂。金属四苯基卟啉及其衍生物是用得最普遍的模型化合物。文献中巳报道过各种四苯基卟啉衍生物的合成方法,但尚未见带烷硫基的四苯基卟啉衍生物的系统合成方法。本文报道这类四苯基卟啉衍生物及其金属配合物的合成。 本文采用通常的一步法合成四苯基卟啉衍生物,即首先参照文献方法合成烷硫基苯甲 Some synthetic metalloporphyrins have been widely used as catalysts in biomimetic oxidation due to their function of activating molecular oxygen. Metal tetraphenylporphyrin and its derivatives are the most widely used model compounds. Synthetic methods for various tetraphenylporphyrin derivatives have been reported in the literature, but no systematic synthesis of tetraphenylporphyrin derivatives with alkylthio groups has been reported. This paper reports the synthesis of tetraphenylporphyrin derivatives and their metal complexes. In this paper, the usual one-step synthesis of tetraphenylporphyrin derivatives, namely the first reference to the literature synthesis of alkylthiobenzoyl