Highly Efficient Organic Ultraviolet Photodetectors Based on Re(I) Complexes

来源 :Chemical Research in Chinese Universities | 被引量 : 0次 | 上传用户:wangdianxitong
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High response organic ultraviolet photodetectors(UV-PDs) were demonstrated with 4,4’,4’’tris[3-methyl-pheny(phenyl)amino]triphenylamine(m-MTDATA) and two Re(I) complexes,(bathocuproine)Re(CO)3 Cl(Re-BCP) and(bathophenanthroline)Re(CO)3 Cl(Re-Bphen) to act as the electron donor and acceptor,respectively.UV-PDs have the configuration of indium tin oxide(ITO)/m-MTDATA(25nm)/m-MTDATA:Re-complex(25―35nm)/Re-complex(20nm)/LiF(1 nm)/Al(200 nm) with different blend layer thicknesses of 25,30 and 35 nm.The optimized PD based on Re-Bphen offers a corrected-dark photocurrent up to 760 μA/cm2 at 10 V,corresponding to a response of 310 mA/W which is among the best values reported for organic UV-PDs.Excellent electron transport ability makes for such high photo-to-electron conversion. High response organic ultraviolet photodetectors (UV-PDs) were demonstrated with 4,4 ’, 4’-triistriphenylamine (m-MTDATA) and two Re (I) complexes, (bathocuproine) Re (CO) 3 Cl (Re-BCP) and (bathophenanthroline) Re (CO) 3 Cl (Re-Bphen) to act as the electron donor and acceptor, / m-MTDATA (25nm) / m-MTDATA: Re-complex (25-35nm) / Re-complex (20nm) / LiF nm. The optimized PD based on Re-Bphen offers a corrected-dark photocurrent up to 760 μA / cm 2 at 10 V, corresponding to a response of 310 mA / W which is among the best values ​​reported for organic UV-PDs. Excellent electron transport ability makes for such high photo-to-electron conversion.
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