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采用电化学极化方法研究了Ni3Al和Pt电极在800℃熔融(Na,K)2CO3中的腐蚀电化学阳、阴极极化特征.在熔融碳酸盐中,阳极极化是金属与CO2-3的氧化、阴极极化则是O2-与CO2-3的还原.金属的阳极溶解与O2-的阴极还原构成了金属腐蚀电化学的阳、阴极过程.
The electrochemical and cathodic polarization characteristics of Ni3Al and Pt electrodes in molten (Na, K) 2CO3 at 800 ℃ were studied by electrochemical polarization method. In molten carbonate, anodic polarization is the oxidation of metal with CO2-3 and cathodic polarization is the reduction of O2- with CO2-3. Metal anodic dissolution and O2- cathodic reduction constitutes a metal corrosion electrochemical positive and negative processes.