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A new zinc 1,3,5-benzenetricarboxylate Zn3(BTC)2(DMSO)4(BTC=1,3,5-benzenetricarboxylate) has been solvothermally synthesized in DMSO and structurally determined by X-ray single-crystal diffraction.It crystallizes in the monoclinic system,space group P21/c with a=10.0861(11),b=10.2527(11),c=16.4013(18),β=95.478(2)°,V=1688.3(3)3,Z=2,Zn3S4C26H30O16,Mr=922.85,Dc=1.815 g/cm3,F(000)=936,μ=2.434 mm-1,R=0.0319 and wR=0.0755.This compound consists of trimeric zinc clusters and BTC linkers.Alternate connection of these trimeric zinc clusters and BTC linkers results in a three-dimensional(3,6)-connected frame-work with rutile topology.
A new zinc 1,3,5-benzenetricarboxylate Zn3 (BTC) 2 (DMSO) 4 (BTC = 1,3,5-benzenetricarboxylate) has been solvothermally synthesized in DMSO and structurally determined by X-ray single-crystal diffraction. in the monoclinic system, space group P21 / c with a = 10.0861 (11), b = 10.2527 (11), c = 16.4013 18, β = 95.478 (2) °, V = 1688.3 Z = 2, Zn3S4C26H30O16, Mr = 922.85, Dc = 1.815 g / cm3, F (000) = 936, μ = 2.434 mm-1, R = 0.0319 and wR = 0.0755.This compound consists of trimeric zinc clusters and BTC linkers. Alternate connection of these trimeric zinc clusters and BTC linkers results in a three-dimensional (3,6) -connected frame-work with rutile topology.