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The title complex cis-bis(tetrahydrothiophene)-bis(nitrate) platinum(II),(tht)2Pt(NO3)2,was the reducing product from potassium hexachloroplatinate(IV) K2PtCl6 where the platinum is tetra-valenced. Crystal data for C8H16N2O6PtS2:monoclinic,space group P21/c,a=9.8833(5),b=8.6744(4),c=18.6407(9) ,β=114.401(3)°,V=1455.35(12) 3,Z=4,Mr=495.44,Dc=2.261 g/cm3,F(000)=944,μ=9.950 mm-1,λ(MoKα)=0.71073 ,T=293(2) K,2θmax=54.96o,GOOF=1.033,R=0.0350 and wR=0.0785 for 2572 observed reflections with I > 2σ(I). X-ray diffraction studies reveal that the title complex has interesting weak metal-metal interactions and two molecules linked by metal-metal interaction exist as a group. Luminescent spectrum illuminates red emission of the complex at room temperature.
The title complex cis-bis (tetrahydrothiophene) -bis (nitrate) platinum (II), (tht) 2Pt (NO3) 2, was the reduced product from potassium hexachloroplatinate (IV) K2PtCl6 where the platinum is tetra-valenced. C8H16N2O6PtS2: monoclinic space group P21 / c a = 9.8833 (5) b = 8.6744 (4) c = 18.6407 (9) β β = 114.401 (3) ° V = 1455.35 123 Z = 4, Mr = 495.44, Dc = 2.261 g / cm3, F (000) = 944, μ = 9.950 mm- 1, λ (MoKα) = 0.71073 °, T = 293 (2) K, 2θmax = 54.96 °, GOOF = 1.033, R = 0.0350 and wR = 0.0785 for 2572 observed reflections with I> 2σ (I). X-ray diffraction studies reveal that the title complex has interesting weak metal-metal interactions and two molecules linked by metal-metal interaction exist as a group. Luminescent spectrum illuminates red emission of the complex at room temperature.