We study the light scattering of an orthogonal anisotropic rough surface with secondary most probable slope distribution It is found that the scattered intensity profiles have obvious secondary maxima, and in the direction perpendicular to the plane of incidence, the secondary maxima are oriented in a curve on the observation plane,which is called the orientation curve.By numerical calculation of the scattering wave fields with the height data of the sample, it is validated that the secondary maxima are induced by the side face element, which constitutes the prismoid structure of the anisotropic surface.We derive the equation of the quadratic orientation curve.Experimentally, we construct the system for light scattering measurement using a CCD.The scattered intensity profiles are extracted from the images at different angles of incidence along the orientation curves.The experimental results conform to the theory.