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本文通过透射电镜研究了石墨—ＳｂＣｌ５层间化合物（简称ＳｂＣｌ５—ＧＩＣ）的结构，由相对强度和级数的关系提出了堆垛模式。从 ＳｂＣｌ５－ＧＩＣ的电子衍射花样得出： ＳｂＣｌ５以六方结构的α和β相以及外延生长的γ-相形式层间到碳层层面之间，其中ａα=ａβ＝１５． １５Ａ，ａγ＝１７．２２Ａ；ａγ与 ａｃ一致，而 ａα和ａβ相对ａｃ转动±１６°。 衍射斑点强度表明γ－相在一级ＳｂＣｌ５－ＧＩＣ中含量最高，而在二级和三级中含量相近，而二级的电导率最高。γ－相是影响电导率提高的主要因素，γ－相含量越高，则它的电导率越低。
In this paper, the structure of graphite-SbCl5 intercalation compound (referred to as SbCl5-GIC) was studied by transmission electron microscopy. The stacking mode was proposed by the relationship between relative intensity and series. From the electron diffraction pattern of SbCl5-GIC, SbCl5 was deposited in the hexagonal α and β phases and the epitaxially grown γ-phase layer to the carbon layer with aα = aβ = 15. 15A, aγ = 17.22A; aγ coincides with ac, while aα and aβ rotate ± 16 ° relative to ac. The diffraction spot intensity shows that the content of γ-phase is the highest in the first grade SbCl5-GIC, while the content is similar in the second and third grades, while the second grade has the highest conductivity. The γ-phase is a major factor that affects the conductivity increase. The higher the γ-phase content, the lower its conductivity.