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在CH_2Cl_2、THF及DMSO中研究了系列光谱烧孔材料苯并卟啉锌配合物的电化学及光谱电化学特性,给出不同结构的苯并卟啉锌配合物的氧化还原电位及相应氧化还原态的光谱,结合光谱数据和氢化还原电位数值估算了与光化学光谱烧孔过程密切相关的分子激发态氧化还原电位。
The electrochemical and spectral electrochemical characteristics of benzoporphyrin zinc complexes were investigated in CH_2Cl_2, THF and DMSO. The redox potential and the corresponding redox potential of zinc complexes of benzoporphyrin with different structures were given. State spectra, combined with spectral data and hydrogenation reduction potential numerical estimate of the molecular chemical oxidation of the hole burning process is closely related to the excited state redox potential.