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在酒石酸－乙二胺－高氨酸－亚硫酸钠－高碘酸钟体系中痕量锌锰和硒出现良好极谱吸附波，波峰敏锐，可测定浓度范围在０．４０～４０μｇ／Ｌ Ｚｎ￣（２＋）１．６～８０μｇ／ＬＭｎ￣（２＋）及０．０２～２．３μｇ／ＬＳｅ（Ⅳ）。对含１１．７μｇ／Ｌ Ｚｎ￣（２＋），７．０μｇ／Ｌ Ｍｎ，１．４５μｇ／Ｌ Ｓｅ（Ⅳ）的矿泉水样测定，其相对标准偏差分别是６．２％和９．２％和７．３％。
In the tartaric acid - ethylenediamine - high - acid - sodium sulfite - periodic acid system of trace zinc and manganese and selenium showed a good polarographic adsorption wave sharp, measurable concentration range of 0.40 ~ 40μg / L Zn ~ ( 2+) 1.6 ~ 80μg / LMn ~ (2+) and 0.02 ~ 2.3μg / LSe (Ⅳ). The relative standard deviations (RSDs) of mineral water samples containing 11.7μg / L Zn ~ (2 +), 7.0μg / L Mn and 1.45μg / L Se (Ⅳ) were 6.2% and 9.2% And 7.3%.