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以１，３，４，６－四硫代戊搭烯－２，５－二酮为原料，经偶联、醇解、烃化或醇解、烃化、偶联等步骤，制得四甲硫基四硫富瓦烯、四乙硫基四硫富瓦烃、二喹喔啉硫醚、４－甲硫基－５－甲氧甲酰硫基－１，３－二硫环戊烯－２－酮、四甲硫基乙烯和４，４＇－二甲硫基－５，５＇－二甲氧甲酰硫基四硫富瓦烯及它的异构体混合物．提出了１，３，４，６－四硫代戊搭烯－２，５－二酮醇解机理．讨论了未得到某些预期产物的原因．报道了３种四硫富瓦烯衍生物的循环伏安图及电化学性质．
With 1,3,4,6-tetrathiopentalene-2,5-dione as raw material, through coupling, alcoholysis, alkylation or alcoholysis, alkylation, coupling and other steps, to obtain Sijia Sulfur-based tetrathiafulvalene, tetraethylthio-tetrathiafulvalene, diquinoxaline sulfide, 4-methylthio-5-methoxycarbonylthio-1,3-dithiolane- 2-ketone, tetramethylthioethylene and 4,4’-dimethylthio-5,5’-dimethoxycarbonylthio tetrathiafulvalene and its isomer mixture. An alcoholysis mechanism of 1,3,4,6-tetrathiapentalene-2,5-dione was proposed. The reason why some of the expected products are not available is discussed. Cyclic voltammograms and electrochemical properties of three tetrathiafulvalene derivatives were reported.