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A hybrid compound [Mn(2,2’-bipy)3]2[β-Mo8O26]?4H2O prepared by the hydro- thermal method consists of a [β-Mo8O26]4- isopolyanion, two isolated manganese-bipyridyl units [Mn(2,2’-bipy)3]2+ and four crystal water molecules. Each [Mn(2,2’-bipy)3]2+ is defined by six nitrogen atoms from three 2,2’-bipyridine molecules forming a distorted MnN6 octahedron. Crys- tallographic data for the title compound: monoclinic, space group P21/c, a = 12.156(2), b = 13.738(3), c = 21.949(4) ?, β = 90.44(3)°, V = 3665.3(13) ?3, Mr = 2302.57, Z = 2, Dc = 2.086 g/cm3, F(000) = 2252, T = 293(2) K, μ(Mo-Kα) = 1.745 mm-1, R = 0.0436, wR = 0.1056, and GOF = 1.074 for 550 parameters and 5515 observed reflections with I > 2σ(I).
A hybrid compound [Mn (2,2’-bipy) 3] 2 [β-Mo8O26] • 4H2O prepared by the hydro-thermal method consists of a [β-Mo8O26] 4- isopolyanion, two isolated manganese-bipyridyl units [Mn (2,2’-bipy) 3] 2+] is defined by six nitrogen atoms from three 2,2’-bipyridine molecules forming a distorted MnN6 octahedron. Crys-tallographic data for the title compound: monoclinic, space group P21 / c, a = 12.156 (2), b = 13.738 (3), c = 21.949 (4) , V = 3665.3 (13)? 3, Mr = 2302.57, Z = 2, Dc = 2.086 g / cm3, F000 = 2252, T = 293K, Mo-Kα = 1.745 mm- 1, R = 0.0436, wR = 0.1056, and GOF = 1.074 for 550 parameters and 5515 observed reflections with I> 2σ (I).