人们久已知道,将钾加入到Fischer-Trop-sch催化剂(铁、钌、铱)中会提高长链烃以及烯烃的生成量。另一方面,我们最近报道了用M_2Pd-cl_4(M为碱金属)类络合物制得的钯催化剂,能够在大气压下由CO-H_2选择性生产甲醇,同时论证了钠和锂阳离子对适于甲醇生产的活性中心的形成,具有重要作用。载铑催化剂在高压下能有效地将CO—H_2合成为C_2氧化物,而在大气压下只能生成甲烷和烃类。根据这一报导,我们研究了掺添碱金属阳离子对载 It has long been known that the addition of potassium to Fischer-Trop-sch catalysts (iron, ruthenium, iridium) increases the production of long chain hydrocarbons and olefins. On the other hand, we recently reported a palladium catalyst prepared from M_2Pd-cl_4 (M is an alkali metal) complex and was able to selectively produce methanol from CO-H 2 at atmospheric pressure. Simultaneously, it was demonstrated that sodium and lithium cations are suitable The formation of the active center of methanol production plays an important role. Rhodium-loaded catalysts can effectively synthesize CO-H_2 to C_2 oxide under high pressure, while methane and hydrocarbons can only be formed at atmospheric pressure. According to this report, we studied the incorporation of alkali metal cation on the load