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前文报道了含芳香叔胺基丙烯酸酯-甲基丙烯酸4-N,N-二甲氨基苄酯(DMABMA)的合成和聚合。这种在分子中既含有二甲氨基苯基,又含有双键的单体为“可聚合芳香叔胺”,在过氧化二酰如过氧化苯甲酰(BPO),过氧化月桂酰(LPO)引发下,芳香叔胺残基参与氧化还原引发体系,进而双键发生聚合反应。本文报道了二甲氨基苯基取代丙烯酰胺,即N-(4-N,N‘-二甲氨基苯基)丙烯酰胺(DMAPAA)和N-(4-N,N-二甲氨基苯基)甲基丙烯酰胺(DMAPMA)的合成及聚合。
The foregoing reports the synthesis and polymerization of aromatic tertiary aminoacrylate-methacrylic acid 4-N, N-dimethylaminobenzyl ester (DMABMA). Such monomers containing both dimethylaminophenyl and double bonds in the molecule are “polymerizable aromatic tertiary amines”, and in diacyl peroxides such as benzoyl peroxide (BPO), lauroyl peroxide (LPO ), The aromatic tertiary amine residues participate in the redox initiation system, and the double bond undergoes polymerization reaction. Dimethylaminophenyl substituted acrylamides, namely, N- (4-N, N’-dimethylaminophenyl) acrylamide (DMAPAA) and N- (4-N, N- dimethylaminophenyl) Synthesis and Polymerization of Methacrylamide (DMAPMA).