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测定了一组八烷氧基萘酞菁镍（Ⅱ）配合物Ni（Ⅱ）（RO）8NPC（R＝C4H9，C8H17，C12H25，NPC＝C48H16N8）在5种有机溶剂（Py、DMSO、DMF、CH2Cl2、C6H12）中的电子吸收光谱和荧光光谱，研究了这些配合物的结构与光谱的关系。结果表明该系列RO取代萘酞菁镍（Ⅱ）配合物的Q带吸收光谱比无取代的红移75nm左右，荧光光谱屯相应红移50～80nm，而溶剂对其影响不大。
A series of complexes of Ni (Ⅱ) (RO) 8NPC (R = C4H9, C8H17, C12H25, NPC = C48H16N8) were prepared in five organic solvents (Py, DMSO, DMF, CH2Cl2, C6H12) electron absorption and fluorescence spectra, the relationship between the structure of these complexes and the spectrum. The results showed that the Q band absorption spectra of the substituted naphthalocyanine nickel (Ⅱ) complexes of this series were about 75 nm redshifted compared with the unsubstituted red shift, while the red spectral shifts of the fluorescence spectra were 50-80 nm. However, the solvent had little effect on the Q band absorption spectra.