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文献中研究了1,1-二氰乙烯基-2,2-二硫醇盐(简称i-mnt)的Cu(Ⅱ)和 Ni(Ⅱ)配合物.现合成出i-mnt的钒(Ⅳ)和铁(Ⅲ)配合物,根据钒(Ⅳ)配合物的ESR谱和铁(Ⅲ)配合物的Mossbauer谱及其他光谱探讨它们的键合和结构。
The Cu (Ⅱ) and Ni (Ⅱ) complexes of 1,1-dicyanovinyl-2,2-dithiolate (i-mnt) ) And iron (Ⅲ) complexes were synthesized and their bonding and structure were investigated based on the ESR spectrum of the vanadium (Ⅳ) complex, the Mossbauer spectrum of the iron (Ⅲ) complex and other spectra.