Transition-metal chalcogenide nanowires (TMCN) as a viable candidate for nanoscale applications have been attracting much attention for the last few decades.Starting from the rigid building block of M6 octahedra (M =transition metal),depending on the way of connection between M6 and decoration by chalcogenide atoms,multiple types of extended TMCN nanowires can be constructed based on some basic rules of backbone construction proposed here.Note that the well-known Chevrel-phase based M6X6 and M6X9 (X =chalcogenide atom) nanowires,which are among our proposed structures,have been successfully synthesized by experiment and well studied.More interestingly,based on the construction principles,we predict three new structural phases (the cap,edge,and C&E phases) of Mo5S4,one of which (the edge phase) has been obtained by top-down electron beam lithography on two-dimensional MoS2,and the C&E phase is yet to be synthesized but appears more stable than the edge phase.The stability of the new phases of Mo5S4 is further substantiated by crystal orbital overlapping population (COOP),phonon dispersion relation,and thermodynamic calculation.The barrier of the structural transition between different phases of MosS4 shows that it is very likely to realize an conversion from the experimentally achieved structure to the most stable C&E phase.The calculated electronic structure shows an interesting band nesting between valence and conduction bands of the C&E MosS4 phase,suggesting that such a nanowire structure can be well suitable for optoelectronic sensor applications.