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通过电子能谱(AES和ESCA)研究了锂-聚吡咯电池的放电反应,认为该电池的放电是锂在聚砒咯中的嵌入过程.嵌入的锂主要是以Li~+存在,其1s电子的结合能为56.0eV.Li~+在嵌合物中的扩散系数D为10~(-12)—10~(-13)cm~2·s~(-1)数量级.
The discharge reactions of lithium-polypyrrole batteries were studied by electron spectroscopy (AES and ESCA), and the discharge of lithium-polypyrrole batteries was considered as the intercalation of lithium in polypyrrole. The intercalated lithium was mainly existed as Li + Of the binding energy is 56.0eV.The diffusivity D of Li ~ + in the chimera is in the order of 10 ~ (-12) -10 ~ (-13) cm ~ 2 · s ~ (-1).