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70年代 Peacock 等合成了具有巨大分子量的以 SiW_(11)O_(39)~(8-)为无机高分子配体的稀土杂多配合物 K_(13)[Ln(SiW_(11)O_(39))_2]·XH_2O,显示了优异的催化性能。可以预见以 MoP 或 MoSi 双—11系列为配体的稀土杂多酸盐必将在氧化性能方面具有更为优秀的性能。
In the 1970s, Peacock et al. Synthesized rare earth heteropoly complexes K_ (13) [Ln (SiW_ (11) O_ (39)) with large molecular weight and SiW 11 O 39 ~ )) _ 2] · XH 2 O, showing excellent catalytic performance. It is foreseeable that rare earth heteropolyacid salt with MoP or MoSi double -11 series ligand will surely have better performance in oxidation performance.