本文着重对直链聚醚配位化学的进展作一概述,综述了该类配合物的合成、组成和结构。特别是对影响配位的各种因素,如氧化乙烯单元数、配合物中配体构象及骨架、末端基效应、溶剂影响与共存阴离子作用等展开探讨,同时对我国学者包括作者近期在镧系元素与直链聚醚配合物的研究进行了介绍。 This article focuses on the development of linear polyether coordination chemistry and summarizes the synthesis, composition and structure of the complexes. In particular, the various factors that affect the coordination, such as the number of ethylene oxide units, the ligand conformation and the skeleton of the complex, the end group effect, the influence of solvents and coexisting anion effects discussed, at the same time our scholars, including the author recently lanthanide The research on the element and linear polyether complex is introduced.