Microstructural evolution of titanium matrix composite coatings reinforced by in situ synthesized Ti

来源 :International Journal of Minerals Metallurgy and Materials | 被引量 : 0次 | 上传用户:libra_15
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Titanium-based composite coatings reinforced by in situ synthesized TiB and TiC particles were successfully fabricated on Ti6Al4V by laser cladding using Ti-B_4C-Al or Ti-B_4C-C-Al powders as the precursor materials.The microstructural and metallographic analyses were made by X-ray diffraction(XRD),optical microscope(OM),scanning electron microscopy(SEM),and electron probe microanalysis (EPMA).The results show that the coatings are mainly composed ofα-Ti cellular dendrites and a eutectic transformation product in which a large number of coarse and fine needle-shaped TiB and a few equiaxial TiC particles are homogeneously embedded.A thin dilution zone with a thickness of about 100μm is present at the interface,and it consists of a few TiB and TiC reinforcements and a large number of lamella grains growing parallel to the heat flux direction in which a thin needle-shaped microstructure exists due to the martensitic transformation. The microstructural evolution can be divided into four stages:precipitation and growth of primaryβ-Ti phase,formation of the binary eutecticumβ-Ti+TiB,formation of the ternary eutecticumβ-Ti+TiB+TiC,and solid transformation fromβ-Ti toα-Ti. Titanium-based composite coatings reinforced by in situ synthesized TiB and TiC particles were successfully fabricated on Ti6Al4V by laser cladding using Ti-B_4C-Al or Ti-B_4C-C-Al powders as the precursor materials. Microstructural and metallographic analyzes were made by X-ray diffraction (XRD), optical microscope (OM), scanning electron microscopy (SEM), and electron probe microanalysis (EPMA). The results show that the coatings are mainly composed of α-Ti cellular dendrites and a eutectic transformation product in which a large number of coarse and fine needle-shaped TiB and a few equiaxial TiC particles are homogeneously embedded. A thin dilution zone with a thickness of about 100 μm is present at the interface, and it consists of a few TiB and TiC reinforcements and a large number of lamella grains growing parallel to the heat flux direction in which a thin needle-shaped microstructure exists due to the martensitic transformation. The microstructural evolution can be divided into four stages: precipitation and growth of primary β-Ti phase, formation of the binary eutecticum β-Ti + TiB, formation of the ternary eutecticum β-Ti + TiB + TiC, and solid transformation from β-Ti to α-Ti.
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