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用固相反应法研究了 Ag_xMoO_3(x=0～0.9)和 Cu_xMoO_3(x=0～0.9)系统,在 Ag_zMoO_3中存在有别于其余组成的黑色相 Ag_(0.1-δ)MoO_3,此组成能用 TREOR 计算机程序指标化为单斜晶系:α=14.8326(?),b=7.S826(?),c=12.7533(?),β=113.03°.对 Cu_xMoO_3系统,铜插入到 MoO_3晶格中使 X 射线衍射谱复杂化.测定了两个系统的电导率,其中 Ag_(0.1-δ)MoO_3的总电导率为9.89S/cm,电子电导率为4.04×10~(-1)S/cm,是好的混合导体,其余组成的电导率随组成呈规律性变化.对实验结果进行了讨论
The system of Ag_xMoO_3 (x = 0 ~ 0.9) and Cu_xMoO_3 (x = 0 ~ 0.9) was studied by the solid-state reaction method. The Ag_zMoO_3 has a black phase of Ag_ (0.1-δ) MoO_3, TREOR computer program is indexed to monoclinic: α = 14.8326 (?), B = 7.S826 (?), C = 12.7533 (?), Β = 113.03 °. For the Cu_xMoO_3 system, copper is inserted into the MoO_3 lattice The X-ray diffraction spectra were complicated.The conductivity of Ag_ (0.1-δ) MoO_3 was 9.89S / cm and the electronic conductivity was 4.04 × 10 ~ (-1) S / cm , Is a good hybrid conductor, the conductivity of the remaining composition changes regularly with the composition of the experimental results were discussed