在溶剂热条件下,利用配合物配体CuL与高氯酸锌反应,合成了一例新的异金属配合物[(CuL)2Zn(ClO4)2],其结构经X-射线单晶衍射、元素分析、红外光谱,紫外—可见光谱等表征.配合物属于单斜晶系,C2/c空间群.晶胞参数分别为a=1.5756(2)nm,b=1.7660(2)nm,c=1.5570(2)nm,α=90°,β=94.137(2),γ=90°.配合物通过分子间氢键连成一维链状结构. In the solvothermal condition, a new complex of [(CuL) 2Zn (ClO4) 2] was synthesized by the reaction of complex ligand CuL with zinc perchlorate. Its structure was characterized by X-ray single crystal diffraction, The results show that the complex belongs to the monoclinic space group C2 / c, and the unit cell parameters are a = 1.5756 (2) nm, b = 1.7660 (2) nm and c = 1.5570 (2) nm, α = 90 °, β = 94.137 (2), γ = 90 °. The complexes are connected into one-dimensional chain structures by intermolecular hydrogen bonding.