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从ＩＲ、ＥＳＲ 和ＸＰＳ的测试结果可知，Ｎｉ２ ＋ 或Ｌａ３＋ 与壳聚糖（ＣＳ） 链节单元上的氨基Ｎ 和仲羟基Ｏ发生配位反应，形成ＣＳ－ Ｎｉ２ ＋ 或ＣＳ－ Ｌａ３ ＋ 配位聚合物膜。通过电导率研究其配位数，发现Ｎｉ２ ＋ 或Ｌａ３ ＋ 可与壳聚糖的３ 个或５ 个链节单元配位。根据以上的实验可推定中心离子Ｎｉ２＋ 与壳聚糖３ 个链节单元上的氨基Ｎ 和仲羟基Ｏ 结合，形成六配位的ＣＳ－ Ｎｉ 配位聚合物；Ｌａ３ ＋ 与壳聚糖５ 个链节单元上的氨基Ｎ 和仲羟基Ｏ配位形成十配位的ＣＳ－ Ｌａ 配位聚合物。从ＩＲ、ＥＳＲ 和ＸＰＳ的测试结果可知，Ｎｉ２ ＋ 或Ｌａ３＋ 与壳聚糖（ＣＳ） 链节单元上的氨基Ｎ 和仲羟基Ｏ发生配位反应，形成ＣＳ－ Ｎｉ２ ＋ 或ＣＳ－ Ｌａ３ ＋ 配位聚合物膜。通过电导率研究其配位数，发现Ｎｉ２ ＋ 或Ｌａ３ ＋ 可与壳聚糖的３ 个或５ 个链节单元配位。根据以上的实验可推定中心离子Ｎｉ２＋ 与壳聚糖３ 个链节单元上的氨基Ｎ 和仲羟基Ｏ 结合，形成六配位的ＣＳ－ Ｎｉ 配位聚合物；Ｌａ３ ＋ 与壳聚糖５ 个链节单元上的氨基Ｎ 和仲羟基Ｏ配位形成十配位的ＣＳ－ Ｌａ 配位聚合物。
The results of IR, ESR and XPS show that Ni2 + or La3 + coordinated with amino group N and secondary hydroxyl group O on chitosan (CS) unit to form CS-Ni2 + or CS-La3 + Polymer film. The conductivity of its coordination number and found that Ni2 + or La3 + with chitosan 3 or 5 units of coordination unit. Based on the above experiments, it can be inferred that the central ion Ni2 + combines with amino group N and secondary hydroxyl group O on the three units of chitosan to form a six-coordinated CS-Ni coordination polymer. La3 + and chitosan The amino group N on the unit of a unit is coordinated with the secondary hydroxyl group O to form a ten-coordinated CS-La coordination polymer. The results of IR, ESR and XPS show that Ni2 + or La3 + coordinated with amino group N and secondary hydroxyl group O on chitosan (CS) unit to form CS-Ni2 + or CS-La3 + Polymer film. The conductivity of its coordination number and found that Ni2 + or La3 + with chitosan 3 or 5 units of coordination unit. Based on the above experiments, it can be inferred that the central ion Ni2 + combines with amino group N and secondary hydroxyl group O on the three units of chitosan to form a six-coordinated CS-Ni coordination polymer. La3 + and chitosan The amino group N on the unit of a unit is coordinated with the secondary hydroxyl group O to form a ten-coordinated CS-La coordination polymer.