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窗口图解技术(Window diagram techni-que)是Laub 等提出的最优化中一种较新的方法,它已经在色谱分析最优化方面取得相当的成就。在色谱分析中,尽管已报道大量保留数据,但还没有可靠的溶液理论对色谱行为的预示超出定量或半定量估计,因而,窗口图解技术很快引起人们的注意。这种技术的出现为GLC、GSC、HPLC 法中分析温度的最优化提供一个有效的方法。它已在GLC 中被用来提高多组分析的分辨能力,对混合固定液的色谱行为作出预示,从而选择最优组成。它不仅成功地应用于已知混合物色谱分析的最优化,而且也成功地应用于未知组分的复杂混合物的最优分析。采用化学键合烃化固定相(Hydrocarbon-
Window diagram techni-que is a newer method of optimization proposed by Laub et al. It has achieved considerable success in the optimization of chromatographic analysis. In chromatographic analysis, although a large number of retention data have been reported, no reliable solution theory predicts chromatographic behavior beyond quantitative or semi-quantitative estimates, and as a result, window-mapping techniques are quickly gaining attention. The emergence of this technology for GLC, GSC, HPLC analysis of the temperature to provide an effective way to optimize. It has been used in GLC to improve the resolving power of multiple sets of analyzes, predicting the chromatographic behavior of mixed fixatives, and selecting the optimal composition. It is not only successfully applied to the optimization of chromatographic analysis of known mixtures, but also successfully applied to the optimal analysis of complex mixtures of unknown components. Using chemically bonded hydrocarbon phase (Hydrocarbon-