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研究了Eu ̄(3+)在EastmanAQ-29D化学修饰电极上的电化学行为。研究表明,在pH4.4的0.1mol.L ̄1NaClO_4底液中,Eu ̄(3+)的还原一氧化过程是一种半无限状态;在最佳测试条件下,Eu ̄(3+)的还原峰高在1.0×10 ̄7~1.0×10 ̄(-5)mol·L ̄(-1)范围内有良好的线世关系。用计时库伦法测定Eu ̄(3+)在聚合物涂层中有效电荷迁越的扩散系数D_(app),其平均值为(3.2±1.1)×10 ̄(-11)m ̄2·s ̄(-1)。
The electrochemical behavior of Eu¯ (3+) at Eastman AQ-29D chemically modified electrode was studied. Studies have shown that 0.1mol at pH4.4. Under the optimal test conditions, the reduction peak of Eu ~ (3 +) is 1.0 × 10 ~ 7 ~ 1 .0 × 10 ~ (-5) mol · L ~ (-1) in the range of good lineage relationship. The chronometric coulometric method was used to determine the diffusion coefficient D app of effective charge transfer of Eu 3+ in the polymer coating with an average of (3.2 ± 1.1) × 10 (-11) m ~ 2 · s ~ (-1).