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Freeze casting can easily control the pore morphology,porosity,microstructure as well as the mechanical properties of porous ceramics.The addition of polyvinyl alcohol(PVA)and polymethyl methacrylate(PMMA)can control the microstructures and properties of porous ceramics.And the freezing temperature also had a great influence on the microstructure.The experimental results indicated that the big and non-interconnected lamellar pores of ceramics without PVA were changed into small and interconnected lamellar pores after adding PVA.