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[Zn(o-bda)(phen)(H2O)]·H2O (C22H20N2O6Zn) (1) [where o-bda is o-phenylenediacetic acid dianion and phen is 1,10-phenanthroline] crystallizes in triclinic system, space group P1 with a=0.826 5(4) nm, b=1.042 4(5) nm, c=1.238 1(6) nm, α=76.987(9)°, β=70.987(9)°, γ=78.281(8)°, V=0.9728(8) nm3, Z=2, Dc=1.617 g·cm-3, μ=1.308 mm-1 and F(000)=488. Zn(Ⅱ)ion has a distorted trigonal bipyramid coordination geometry formed by two carboxyl O atoms from two different o-bda groups, two N atoms from the phen ligand and one terminal water molecule. Adjacent Zn(Ⅱ) ions are interlinked by o-bda groups into a infinite zigzag chain structure with a Zn...Zn distance of 0.825 6(4) nm. The adjacent zigzag chains may also be paired under direction of supramolecular recognition and attraction through both π-π stacking and hydrogen bonding interactions into molecular zippers, which further interlinked into a three-dimensional supramolecular network by these noncovalent interactions. CCDC: 600935.
[Where o-bda is o-phenylenediacetic acid dianion and phen is 1,10-phenanthroline] crystallizes in a triclinic system, space group P1 [Zn (o-bda) (phen) a = 76.987 (9) °, β = 70.987 (9) °, γ = 78.281 (8) with a = 0.826 5 (4) nm and b = 1.042 4 (V) = 0.9728 (8) nm3, Z = 2, Dc = 1.617 g · cm-3, μ = 1.308 mm-1 and F (000) = 488. Zn (Ⅱ) ion has a distorted trigonal bipyramid coordination geometry by two carboxyl O atoms from two different o-bda groups, two N atoms from the phen ligand and one terminal water molecule. Adjacent Zn (II) ions are interlinked by o-bda groups into an infinite zigzag chain structure with a Zn. .Zn distance of 0.825 6 (4) nm. The adjacent zigzag chains may also be paired under direction of supramolecular recognition and attraction through both π-π stacking and hydrogen bonding interactions into molecular zippers, which further interlinked into a three-dimensional supramolecular network by these noncovalent interactions. CCDC: 600935.