The crustal structure of the northwestern sub-basin area of the South China Sea was modeled by inverting a wide-angle seismic survey line across the entire region and on both sides of its bounding continental margins. The survey line extended over 484 km. A total of 14 Ocean Bottom Seismometers (OBS) were deployed at intervals of 30 km to record air-gun array sources with a combined volume of 5160 in 3 . The crustal velocity structure of the northwestern sub-basin area was acquired through the integration of multi-channel seismic data. OBS data were processed and modeled initially using ray tracing inversion techniques. Results indicate that crustal thickness under the continental slope decreases from 21 to 11 km, crustal thickness of the northwestern sub-basin is 7.7 km, and the depth to the Moho ascends from 21 km under the upper continental slope to 11 km under the middle basin. The crust of the northwestern sub-basin is similar to that of the eastern sub-basin in its oceanic crustal structure. This structure has a thicker layer 1 (sedimentary layer) and a thinner layer 2. These characteristics are especially clear in the eastern sub-basin, which differs somewhat from typical oceanic crust. The tectonic geometry and velocity structure of the northwestern sub-basin and its margins comprise a symmetrical conjugate and indicate a pure shear mode with regard to the continental margin rifting mechanism. We did not find clear seismic signals from high velocity layers under the lower crust of the continental margin in the northern part of the northwestern sub-basin, which provides new evidence for the idea that the western part of the northern continental margin of the South China Sea constitutes nonvolcanic crust. Because the seafloor spreading period of the northwestern sub-basin was short, layer 2 might have experienced asymmetrical basalt magma flows, which may have blurred the magnetic anomaly lineations of the northwestern sub-basin. The crustal structure of the northwestern sub-basin area of ​​the South China Sea was modeled by inverting a wide-angle seismic survey line across the entire region and on both sides of its bounding continental margins. The survey line extended over 484 km. A total of 14 Ocean Bottom Seismometers (OBS) were deployed at intervals of 30 km to record air-gun array sources with a combined volume of 5160 in 3. The crustal velocity structure of the northwestern sub-basin area was acquired through the integration of multi- Results indicate that crustal thickness under the continental slope decreases from 21 to 11 km, crustal thickness of the northwestern sub-basin is 7.7 km, and the depth to the Moh ascends from 21 km under the upper continental slope to 11 km under the middle basin. The crust of the northwestern sub-basin is similar to that of the eastern sub-basin in its oceanic crusta This structure has a thicker layer 1 (sedimentary layer) and a thinner layer 2. These characteristics are especially clear in the eastern sub-basin, which differs somewhat from typical oceanic crust. The tectonic geometry and velocity structure of the northwestern sub -basin and its margins comprise a symmetrical conjugate and indicate a pure shear mode with regard to the continental margin rifting mechanism. We did not find clear seismic signals from high velocity layers under the lower crust of the continental margin in the northern part of the northwestern sub-basin, which provides new evidence for the idea that the western part of the northern continental margin of the South China Sea non- nonvolcanic crust. Because of seafloor spreading period of the northwestern sub-basin was short, layer 2 might have experienced asymmetrical basalt magma flows, which may have blurred the magnetic anomaly lineations of the northwestern sub-basin.