论文部分内容阅读
Sgnthesis of five 7-membered compounds containing silane, sulfur and phosphorus groupswas achieved by using endo, endo-bicyclo[3.3.0]octanediol 2. These tricyclic molecules areconsidered as ideal substraes for kinetic resolution of the diol. A discussion of the spectral dataabout these compounds was given and four of them would be substrate molecules containing an sp’hybridized prochiral center and could be used for molecules for a kinetic resolution combiningconfigurational d iastereotopo s -differentiating and diastereo isom er-differentiating reaction s.
Sgnthesis of five 7-membered compounds containing silane, sulfur and phosphorus groupswas achieved by using endo, endo-bicyclo [3.3.0] octanediol 2. These tricyclic molecules areconsidered as ideal substraes for kinetic resolution of the diol. A discussion of the spectral dataabout these compounds was given and four of them would be substrate molecules containing an sp’hybridized prochiral center and could be used for molecules for a kinetic resolution combiningconfigurational diastereotopo s-differentiation and diastereo isom er-differentiating reaction s.