Cycloartane triterpenes from marine green alga Cladophora fascicularis

来源 :Chinese Journal of Oceanology and Limnology | 被引量 : 0次 | 上传用户:zhanghai_007
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Six cycloartanes were isolated from ethanol extract of marine green alga Cladophora fas-cicularis by column chromatography. Procedure of isolation and description of these compounds are given in this paper. The structures were elucidated as (1). 24-hydroperoxycycloart-25(26)-en-3β-ol; (2). cycloart-25(26)-en-3β 24-diol; (3). 25-hydroperoxycycloart-23-en-3β-ol; (4). cycloart-23-en-3β, 25-diol; (5). cycloart-23, 25(26)-dien-3β-ol; and (6). cycloart-24-en-3β-ol by spectroscopic (MS, 1D and 2D NMR) data analysis. Cycloartane derivatives are widely distributed in terrestrial plants, but only few were ob-tained in the alga. All these compounds that have been isolated from terrestrial plants, were found in the marine alga for the first time. Six cycloartanes were isolated from ethanol extract of marine green alga Cladophora fas-cicularis by column chromatography. Procedure for isolation and description of these compounds are given in this paper. The structures were elucidated as (1). 24-hydroperoxycycloart-25 (26) (2) cycloart-25 (26) -en-3β 24-diol; (3) 25-hydroperoxycycloart-23-en-3β-ol; (6). Cycloart-24-en-3β-ol by spectroscopic (MS, 1D and 2D NMR) data analysis. Cycloartane derivatives are widely distributed in terrestrial plants, but only few were ob-tained in the alga. All these compounds that have been isolated from terrestrial plants, were found in the marine alga for the first time.
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