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用量子化学计算研究了碳正离子 1,2 重排的氢、甲基迁移重排机理,结果表明其历程是一种正离子系统中的原子迁移的协同历程,从而说明了一般有机理论中认为其历程为负离子型的迁移的观点是不确切的
Quantum chemical calculations were used to study the rearrangement mechanism of hydrogen and methyl migrations of carbon-1 and carbon-1,2 rearrangements. The results show that this process is a synergistic process of atom transport in the positive ion system, Its history is negative ion migration point of view is not precise