论文部分内容阅读
本文研究了叔胺N235和正辛醇在石油醚稀释剂中,协萃柠檬酸的机理。协萃配合物组成为H3A·2N235·n-octanol,是一个加成反应,Kf=2.62×103。并推测出协萃配合物的结构式,解释了协萃现象
In this paper, the mechanism of synergistic extraction of citric acid with tertiary amine N235 and n-octanol in petroleum ether diluent was studied. The coexisting complex is composed of H3A · 2N235 · n-octanol, which is an addition reaction with Kf = 2.62 × 103. And deduced the formula of the complex compound, which explains the phenomenon of synergistic extraction