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用七(2,6-二-O-戊基-3-O-三氟乙酰基)-β-环糊精分离了胺类、氨基酸类、环氧化物和卤代烃等对映体,测定了α、-Δ(ΔH)、-Δ(ΔS)及Δ(ΔH)/Δ(ΔS)值,通过和文献数据比较,观察到同系物的Δ(ΔH)/Δ(ΔS)值接近于一个常数,且和所用手性固定相及是否发生“包结”作用无关。
Enantiomers such as amines, amino acids, epoxides and halohydrocarbons were isolated using heptakis (2,6-di-O-pentyl-3-O-trifluoroacetyl) -β-cyclodextrin, The Δ (ΔH) / Δ (ΔS) values of the homologues were observed to be close to one by comparison with the literature data for α, -Δ (ΔH), - Δ (ΔS) and Δ (ΔH) Constant, and with the chiral stationary phase and whether the occurrence of “inclusion” has nothing to do.