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本文用计算机数字模拟方法研究了电活性分子多层Ｚ型Ｌ－Ｂ膜修饰电极的循环伏安行为。计算了电极与修饰Ｌ－Ｂ膜分子第一层之间的电荷转移速度常数Ｋ_ｏ，Ｌ－Ｂ膜分子层间的电荷转移速度常数ｋ_ｉ；对峰电位差△Ｅ_ｐ及阳极峰面积Ｑ的影响，以及在不同条件下各层分子的氧化态分数随扫描时间的变化。为研究和设计电活性分子修饰电极的实际体系提供了大量数据和信息。
In this paper, the cyclic voltammetry behavior of a multi-layer Z-type L-B film modified electrode was investigated by computer numerical simulation. The charge transfer rate constant K_o between the electrode and the first layer of the modified L-B film and the charge transfer constant k_i between the L-B film layers were calculated. The influence on the peak potential difference △ E_p and the anode peak area Q was calculated, And the change of the oxidation state of each layer with the scanning time under different conditions. It provides a wealth of data and information for the study and design of the actual system of electroactive molecular modification electrodes.