四氟乙烯与甲醇在游离基引发剂的作用下发生調节聚合反应,生成一系列的低級調聚产物,即含有奇数碳原子的α,α,ω三氫全氟醇类: nC_2F_4+CH_3OH→H(CF_2—CF_2)_nCH_2OH(n=1—12)这些产物具有多氟化合物特有的稳定性和不燃性,又含有活泼的伯醇基,所以是氟有机化学中的一类重要合成中間体,又是制备某些特殊材料如高溫潤滑剂、介 Tetrafluoroethylene and methanol under the action of free radical initiator to regulate the polymerization reaction to generate a series of low-level telomerization products, that is, containing an odd number of carbon atoms α, α, ω trihydric perfluoroalcohol: nC_2F_4 + CH_3OH → H (CF_2-CF_2) _nCH_2OH (n = 1-12) These products have the unique stability and incombustibility of polyfluorinated compounds, as well as active primary alcohol groups. Therefore, these products are a kind of important synthetic intermediates in fluorine organic chemistry, Is to prepare some special materials such as high temperature lubricants, mediated