【摘 要】
：
报道了一维化合物｛［Ｃｕ（ｔｒａｎｓ［１４］ｄｉｅｎｅ）ＳＣＮ］２Ｍｎ（ＳＣＮ）４（４，４′－ｂｉｐｙ）·４Ｈ２Ｏ｝ｎ（ｔｒａｎｓ［１４］ｄｉｅｎｅ为５，７，７，１２，１４，１４－六甲基－１，４，８，１１－四氮杂十四环－４，１１－二烯，４，４′－ｂｉｐｙ为４，４′－联吡啶）的合成、表征和结构分析．该晶体属三斜晶系，具有Ｐ１空间群．ａ＝０．９５９２０（１０）ｎｍ，ｂ＝１．０６８００（１０）ｎｍ，ｃ＝１．７３１６（２）ｎｍ，α＝８４．４００（１０）°，β＝７４．８５０（１０）°，γ＝６９．６５０（１０）°，Ｖ
【机 构】
：
南开大学化学系,中国科学院成都分院分析测试中心
论文部分内容阅读
报道了一维化合物｛［Ｃｕ（ｔｒａｎｓ［１４］ｄｉｅｎｅ）ＳＣＮ］２Ｍｎ（ＳＣＮ）４（４，４′－ｂｉｐｙ）·４Ｈ２Ｏ｝ｎ（ｔｒａｎｓ［１４］ｄｉｅｎｅ为５，７，７，１２，１４，１４－六甲基－１，４，８，１１－四氮杂十四环－４，１１－二烯，４，４′－ｂｉｐｙ为４，４′－联吡啶）的合成、表征和结构分析．该晶体属三斜晶系，具有Ｐ１空间群．ａ＝０．９５９２０（１０）ｎｍ，ｂ＝１．０６８００（１０）ｎｍ，ｃ＝１．７３１６（２）ｎｍ，α＝８４．４００（１０）°，β＝７４．８５０（１０）°，γ＝６９．６５０（１０）°，Ｖ＝１．６０５３（３）ｎｍ３，Ｚ＝１，Ｄｃ＝１．３６５ｇ／ｃｍ３，Ｆ（０００）＝６９１，最终Ｒ［Ｉ＞２σ（Ｉ）］＝０．０４７４，Ｒ（全部）＝０．０６２５，ＧＯＦ（Ｆ２）＝１．２２２．该化合物含［Ｍｎ（ＳＣＮ）４（４，４′－ｂｉｐｙ）ｎ］２－链和两个［Ｃｕ（ｔｒａｎｓ［１４］ｄｉｅｎｅ）ＳＣＮ］＋阳离子．
Reported that one-dimensional compounds {[Cu (trans [14] diene) SCN] 2Mn (SCN) 4 (4,4’-bipy) · 4H2O} n (trans [14] diene is 5,7,7,12,14 , 14-hexamethyl-1,4,8,11-tetraazatetracyclo-4,11-diene and 4,4’-bipy to 4,4’-bipyridyl) analysis. The crystal is triclinic with a space group P1. a = 0.95920 (10) nm, b = 1.06800 (10) nm, c = 1.7316 (2) nm, γ = 69.650 (10) °, V = 1.6053 (3) nm3, Z = 1, Dc = 1.365g / cm3, F (000) = 691, final R [I> 2σ (I)] = 0.0474, R (all) = 0.0625, GOF (F2) = 1.222. This compound contains [Mn (SCN) 4 (4,4’-bipy) n] 2-chain and two [trans (14) diene) SCN] + cations.
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