In order to remediate heavy metal ions from waste water, Al2O3-SiO2 composite aerogels are prepared via a sol-gel and an organic solvent sublimation drying method. Various characterisation techniques have been employed including X-ray diffraction (XRD), Fourier trans-form infrared spectrometry (FTIR), scanning electron microscope (SEM), Energy-dispersion X-ray spectroscopy (EDX), Brunauer-Emmett-Teller (BET) N2 adsoprtion isotherm, and atomic absorption spectrometer (AAS). XRD and FTIR suggest that the aerogels are composed of mainly Al2O3 and minor SiO2. They have a high specific surface area (827.544 m2/g) and high porosity (86.0％) with a pore diameter of～20 nm. Their microstructures show that the distribution of Al, Si, and O is homogeneous. The aerogels can remove～99％Cu2+within～40 min and then reach the equilibrium uptake (～69 mg/g). Preliminary calculations show that the Cu2+uptake by the aerogels follows pseudo second-order kinetics where chemical sorption may take effect owing largely to the high surface area, high porosity, and abundant functional groups, such as Al-OH and Si-OH, in the aerogel network. The prepared aerogels may serve as efficient absorbents for Cu2+removal.