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Two new ion-pair complexes [Co(BBP)2]2[Ni(mnt)2]Cl2·4DMF·2H2O(1, BBP =2,6-bis(benzimidazol-2’-yl) pyridine, mnt = maleonitriledithiolate) and [(Py)2CH2][Co(mnt)2]2·4DMF(2) have been synthesized and characterized by elemental analyses, IR spectroscopy,thermogravimetric analyses and single-crystal X-ray diffraction. X-ray diffraction studies show that complex 1 crystallizes in monoclinic, space group P21/c. The crystal of 2 belongs to a triclinic system with space group P1. Due to the hydrogen bonding interactions, anions and cations formed the mixed packing in complex 1 while the anions and cations formed segregated columns in 2. In addition, thermogravimetric analyses of the two complexes are also investigated.
Two new ion-pair complexes [Co (BBP) 2] 2 [Ni (mnt) 2] Cl2.4DMF.2H2O (1, BBP = 2,6- bis (benzimidazol- 2’-yl) pyridine, mnt = maleonitriledithiolate) X-ray diffraction studies show that [(Py) 2CH2] [Co (mnt) 2] 2.4DMF (2) have been synthesized and characterized by elemental analyzes, thermogravimetric analyzes and single-crystal X-ray diffraction complex 1 crystallizes in monoclinic, space group P21 / c. The crystal of 2 belongs to a triclinic system with space group P1. Due to the hydrogen bonding interactions, anions and cations formed the mixed packing in complex 1 while the anions and cations formed segregated columns in 2. In addition, thermogravimetric analyzes of the two complexes are also investigated.