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Two new macrocyclic compounds, [Cu2(L)2](ClO4)4·2CH3OH (1) and [Cu(L)](ClO4)2·2H2O (2) (L = 1,3,10,12,15,18-hexaazatetracyclodocosane) were synthesized by condensation reactions involving amines and formaldehyde in the presence of copper anion. Compound 1 crystallizes in triclinic, space group Pí with a = 10.442(2), b = 14.197(3), c = 17.388(4), α = 91.218(4), β = 90.69(3), γ = 93.756(4)o, V = 2520.4(9)3, Z = 2, F(000) = 1260, Dc = 1.589 Mg/m3, Mr = 1205.92, μ = 1.137 mm-1, λ = 0.71073, the final R = 0.0668 and wR = 0.1573 for 9703 observed reflections with I > 2σ(I). Compound 2 crystallizes in monoclinic, space group C2/c with a = 16.911(2), b = 11.4172(15), c = 27.059(4), β = 107.787(2)o, V = 4974.7(12)3, Z = 8, F(000) = 2504, Dc = 1.610 Mg/m3, Mr = 602.92, μ = 1.155 mm-1, λ = 0.71073 , the final R = 0.0419 and wR = 0.1131 for 4374 observed reflections with I > 2σ(I).
Two new macrocyclic compounds, [Cu2 (L) 2] (ClO4) 4 · 2CH3OH (1) and [Cu (L)] (ClO4) 2 · 2H2O (2) 18-hexaazatetracyclodocosane was synthesized by condensation reactions involving amines and formaldehyde in the presence of copper anion. Compound 1 crystallizes in triclinic, space group P = with a = 10.442 (2), b = 14.197 (3), c = 17.388 (4) Α = 91.218 (4) β = 90.69 (3) γ = 93.756 (4) o V = 2520.4 (9) 3 Z = 2 F (000) = 1260 Dc = 1.589 Mg / m3 , M = 1.137 mm-1, λ = 0.71073, the final R = 0.0668 and wR = 0.1573 for 9703 at refs with I> 2σ (I). Compound 2 crystallizes in monoclinic, space group C2 / c with a = 16.911 (2), b = 11.4172 (15), c = 27.059 (4) , β = 107.787 (2) o, V = 4974.7 (12) Dc = 1.610 Mg / m3, Mr = 602.92, μ = 1.155 mm-1, λ = 0.71073 , the final R = 0.0419 and wR = 0.1131 for 4374 observed reflections with I> 2σ (I).