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非对称杂化的手性膦-亚磷酰胺酯配体因其合成简便、易于调控、结构稳定等优点,被广泛应用于不对称催化反应中,如:不对称氢化、不对称氢甲酰化、不对称烯丙基烷基化、不对称氢膦酰化、不对称[3+2]-环加成、不对称1,4-加成和1,4-还原反应等.综述了手性膦-亚磷酰胺酯配体的种类、合成及其在不对称催化反应中的应用.
Asymmetric heterochiral chiral phosphine-phosphoramidite ligands are widely used in asymmetric catalysis due to their advantages of simple synthesis, easy regulation and structural stability, such as asymmetric hydrogenation, asymmetric hydroformylation , Asymmetric allylalkylation, asymmetric hydrophosphonylation, asymmetric [3 + 2] -cyclic addition, asymmetric 1,4-addition and 1,4-reduction, etc. The chiral Phospho - phosphoramidite ligand species, synthesis and its application in asymmetric catalysis.