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A new nickel coordination compound [Ni(L2-)(2,2′-bipy)(H2O)]·2H2O (H2L=phenyliminodiacetic acid) was obtained by self-assembly of phenyliminodiacetic acid, 2,2′-bipy, and NiCl2·6H2O in the mixed solvent of water and ethanol (V∶V=1∶1). The complex was characterized by elemental analysis, IR spectra, and X-ray crystallography analysis. The crystal is monoclinic, space group P21 / c with a=0.867 4(2) nm, b=0.907 3(1) nm, c=2.643 5(5) nm, β=91.01(1)°, V=2.080 2(4) nm3, Z=4, F(000)=992, Dc=1.520 Mg·m-3, R1=0.027 0 and wR2=0.067 5. In the complex, nickel atom is coordinated with a distorted octahedral geometry and extensive hydrogen bonds link the complexes into a 2D network structure. CCDC: 244926.
A new nickel coordination compound was obtained by self-assembly of phenyliminodiacetic acid, 2,2’-bipy, and NiCl 2 (2,2’-bipy) (H 2 O) · 2H 2 O · 6H2O in mixed solvent of water and ethanol (V: V = 1: 1). The complex was characterized by elemental analysis, IR spectra, and X-ray crystallography analysis. The crystal is monoclinic, space group P21 / c with a = 0.867 4 (2) nm, b = 0.907 3 (1) nm, c = 2.643 5 (5) nm, β = 91.01 ) = 992, Dc = 1.520 Mg · m-3, R1 = 0.027 0 and wR2 = 0.067 5. In the complex, nickel atom is coordinated with a distorted octahedral geometry and extensive hydrogen bonds link the complexes into a 2D network structure. CCDC : 244926.