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在水和甲醇的混合溶剂中，经邻菲绕啉、丁二酸钠和ＣｕＯｌ２·２Ｈ２Ｏ反应合成得到标题配合物，［Ｃｕ２（ｐｈｅｎ）２（ＯＨ）Ｃｌ（Ｃ４Ｈ４Ｏ４）］·８Ｈ２Ｏ．单晶 Ｘ－射线衍射分析表明，晶体属单斜晶系， Ｐ２１（ Ｎｏ． ４）空间群，晶胞参数：α＝０．７７０８（１）ｎｍ，ｂ＝１．７８６１（３）ｎｍ， ｃ＝１．２４８９（２）ｎｍ，β＝９６８９（１）°，Ｖ＝ １．７０７０（５） ｎｍ３，Ｄｃ＝１．５５７ ｇ／ｃｍ２，Ｚ＝２，Ｆ（０００）＝８２４，４２８２个独立衍射点中，３３４８个可观测点满足Ｆ２０≥２σ（Ｆ２０），Ｒ＝０．０６２，ωＲ２＝０．１６３４．［Ｃｕ２（ｐｈｅｎ）２（ＯＨ）Ｃｌ（Ｃ４Ｈ４Ｏ４）］·８Ｈ２Ｏ配合物由双核铜［Ｃｕ２（ｐｈｅｎ）２（ＯＨ）Ｃｌ（Ｃ４Ｈ４Ｏ４）］络分子和晶格Ｈ２Ｏ分子组成．每个Ｃｕ原子与邻菲绕啉上的２个Ｎ原子、丁二酸根上的１个羧基Ｏ原子、１个桥联Ｃｌ原子及桥联氢氧根上的Ｏ原子配位形成高度畸变的三角双锥．通过Ｃｌ原子、氢氧根及丁二酸根一端羧基的桥联作用，相邻三角双锥形成“蝎子”形的双核［Ｃｕ２（ｐｈｅｎ）２（ＯＨ）Ｃｌ（Ｃ４Ｈ４Ｏ４）］络分子．分子间的芳环堆积作用致使双核络分子排列形成平行于晶?
The title complex, [Cu2 (phen) 2 (OH) Cl (C4H4O4)] · 8H2O was synthesized by the reaction of phenanthroline, sodium succinate and CuO12 · 2H2O in a mixed solvent of water and methanol. Single crystal X-ray diffraction analysis showed that the crystal belongs to the monoclinic space group P21 (No. 4) with unit cell parameters of α = 0.7708 (1) nm and b = 1.7861 (3) nm. = 1.2489 (2) nm, β = 9689 (1) °, V = 1.7070 (5) nm3, Dc = 1.557 g / cm2, Z = 2, F (000) = 824,4282 independent Of the diffraction spots, 3348 observable points satisfy F20≥2σ (F20), R = 0.062, and ωR2 = 0.1634. The [Cu2 (phen) 2 (OH) Cl (C4H4O4)] · 8H2O complex is composed of Cu2 (phen) 2 (OH) Cl (C4H4O4) molecules and lattice H2O molecules. Each Cu atom coordinates with two N atoms on phenanthroline, one carboxyl O atom on succinate, one bridged Cl atom and O atom on bridged hydroxyl to form highly distorted triangular bis Cone. Through the bridging effect of Cl atom, hydroxyl group and carboxyl group on the one side of succinate, the adjacent triangular double cones form a “scorpion” binuclear [Cu2 (phen) 2 (OH) Cl (C4H4O4)] molecule. Aromatic ring accumulation between the molecules led to the formation of dual nuclear molecules parallel to the crystal?