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Various functionalized asymmetrical biaryls can be synthesized in high to excellent yields via coupling reaction of aryl iodides or bromides with NaBPh4 catalyzed by MCM-41-supported sulfur palladium(0)complex.This palladium complex can be easily recovered and reused many times without loss of activity.
Various functionalized asymmetrical biaryls can be synthesized in high yield excellent via via reaction of aryl iodides or bromides with NaBPh4 catalyzed by MCM-41-supported sulfur palladium (0) complex. This palladium complex can be easily recovered and reused many times without loss of activity.