【摘 要】
：
本文合成了2个新的席夫碱,N,N′-二(5-氯水杨基)-1,3-二氨基戊烷(H2CAP)和N,N′-二(5-溴水杨基)-1,3-二氨基戊烷(H2BAP),以及它们的铜(Ⅱ)配合物,[Cu(CAP)](1),[Cu(BAP)](2)
【机 构】
：
辽宁师范大学化学化工学院,南京大学配位化学国家重点实验室,
论文部分内容阅读
本文合成了2个新的席夫碱,N,N′-二(5-氯水杨基)-1,3-二氨基戊烷(H2CAP)和N,N′-二(5-溴水杨基)-1,3-二氨基戊烷(H2BAP),以及它们的铜(Ⅱ)配合物,[Cu(CAP)](1),[Cu(BAP)](2)和[Cu(CAP)0.5(BAP)0.5](3),并通过元素分析、红外和电子光谱表征了它们的结构。对于配合物,还利用单晶X-射线衍射进行了结构测试。在每个配合物中,铜原子都采取四面体畸变的平面四边形配位构型。通过将配合物1和2结合在一起形成了聚集体3。在该聚集体中存在有趣的氯和溴取代基交替排列现象。
In this paper, two novel Schiff bases, N, N’-bis (5-chlorosalicylal) -1,3-diaminopentane (H2CAP) and N, (CuBAP)] (2) and [Cu (CAP)] (1) 0.5 (BAP) 0.5] (3), and their structures were characterized by elemental analysis, infrared and electron spectroscopy. For the complexes, structural testing was also performed using single crystal X-ray diffraction. In each complex, the copper atoms take the tetrahedrally distorted planar tetragonal coordination configuration. Aggregates 3 were formed by combining the complexes 1 and 2 together. There is an interesting alternating arrangement of chlorine and bromine substituents in this aggregate.
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